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唐林

时间:2019-01-10 10:51:02来源: 作者:阅读:

       唐林,男,出生于1986年7月,湖南衡阳人,博士,副教授,硕士生导师。河南省青年骨干教师,信阳市学术技术带头人,信阳市优秀青年科技专家,河南省优秀硕士学位论文指导教师。2006年9月就读于湖南师范大学best365中国官网,于2010年7月获得理学学士学位;2010年9月进入中国科技大学化学与材料科学学院硕博连读,于2015年6月获得有机化学博士学位。2015年6月起任职于信阳师范学院best365中国官网。主要从事非均相负载型金属纳米粒子的制备及有机催化性能的应用、有机氟化学以及水相绿色有机合成方法学等研究。目前在国内外学术期刊上发表学术论文30余篇,获得授权中国专利8项。欢迎对有机催化与合成感兴趣的本科生和研究生加盟本课题组。

联系方式:

Email: lintang@xynu.edu.cnTel. : 18790098306

研究兴趣:

1. 非均相纳米催化

2. 过渡金属催化

3. 有机氟化学

主讲课程:

1、 有机化学

2、 高等有机化学

3、 有机化学实验

在研项目:

1. 国家自然科学基金青年基金项目:零价过渡金属催化无外加氧化剂的碳-氢键活化和脱氢偶联构建碳-杂键研究(主持)

2. 河南省科技厅科技攻关项目:石墨烯金属纳米复合材料可控性制备及在医药中间体合成中的应用研究(主持)

3. 河南省教育厅高等学校重点科研项目:负载型金属纳米粒子催化氢转移反应构造氮杂环化合物研究(主持)

代表性论文:

1. Lin Tang,* Ge Lv, Ruimin Cheng, Fang Yang, Qiuju Zhou, Three-Component Perfluoroalkylvinylation of Alkenes Enabled by Dual DBU/Fe Catalysis, Chem. Eur. J. 2022, DOI: 10.1002/chem.202203332.

2. Lin Tang,* Ge Lv, Ya Fu, Xue-Ping Chang,* Ruimin Cheng, Lingling Wang,* Qiuju Zhou, Bifunctional 1,8-Diazabicyclo[5.4.0]undec-7-ene for Visible Light-Induced Heck-Type Perfluoroalkylation of Alkenes, J. Org. Chem. 2022, 87, 14763.

3. Lin Tang,* Fang Yang, Shuai Zhang, Ge Lv, Qiuju Zhou, Lingyun Zheng, Fe-Catalyzed Radical Trifluoromethyl-Alkenylation of Alkenes or Alkynes with 2‑Amino-1,4-naphthoquinones, J. Org. Chem. 2022, 87, 7274.

4. Lin Tang,* Fang Yang, Zhen Yang, Hanfei Chen, Hao Cheng, Shuaifei Zhang, Qiuju Zhou, Weihao Rao, Application of Bifunctional 2‑Amino-1,4-naphthoquinones in Visible-Light-Promoted Photocatalyst-Free Alkene PerfluoroalkylAlkenylation, Org. Lett. 2021, 23, 519.

5. Yang Fang, Qiuju Zhou, Heyan Wang, Lin Tang,* Copper-Catalyzed Cross-Dehydrogenative Phosphorylation of 2-Amino-1,4-naphthoquinones with H-Phosphonates, Eur. J. Org. Chem. 2021, 2021, 5618.

6. Lin Tang, Fang Yang, Hao Cheng, Chen Tan, Chaochao Jin, Hanfei Chen, Yifan Huang, Shuaifei Zhang, Weihan Song, Jiajing Tan,* Copper-Catalyzed Oxidative Fragmentation of Alkynes with NFSI Provides Aryl Ketones, Org. Lett. 2020, 22, 8618.

7. Ya wu, Mengsha Zhang, Yanli Zhang, Mingyang Li, Weisheng Feng, Xiaoke Zheng, Lin Tang,* NBS-activated cross-dehydrogenative esterification of carboxylic acids with DMSO, Org. Chem. Front. 2020, 7, 2719.

8. Xiantao Ma,* Jing Yu, Cuijie Han, Qiuju Zhou, Mengjuan Ren, Lixin Li, Lin Tang,* Dehydrative Synthesis of Functionalized Skipped Dienes from Stabilized Phosphonium Ylides and Allylic Alcohols in Water, Adv. Synth. Catal. 2019, 361, 1023.

9. Ya wu, Yanli Zhang, Zhen Yang, Jingchao Jiao, Xiaoke Zheng, Weisheng Feng, Mengsha Zhang, Hao Cheng, Lin Tang,* Dual Roles of tert-Butyl Nitrite in the Transition Metal- and External Oxidant-Free Trifluoromethyloximation of Alkenes, ChemSusChem 2019, 12, 3960.

10. Lixin Li,* Yan-Na Ma, Mi Tang, Jing Guo, Zhen Yang, Yizhe Yan, Xiantao Ma, Lin Tang,* Photoredox-Catalyzed Oxydifluoroalkylation of Styrenes for Access to Difluorinated Ketones with DMSO as an Oxidant, Adv. Synth. Catal. 2019, 361, 3723.

11. Lin Tang,* Zhen Yang, Jingchao Jiao, Ying Cui, Guodong Zou, Qiuju Zhou, Yuqiang Zhou,* Weihao Rao, Xiantao Ma,* Chemoselective Mono- and Difluorination of 1,3-Dicarbonyl Compounds, J. Org. Chem. 2019, 84, 10449.

12. Zhen Yang, Siwei Chen, Fang Yang, Chenxi Zhang, You Dou, Qiuju Zhou, Yizhe Yan, Lin Tang,* PPh3/Selectfluor-Mediated Transformation of Carboxylic Acids into Acid Anhydrides and Acyl Fluorides and Its Application in Amide and Ester Synthesis, Eur. J. Org. Chem. 2019, 2019, 5998.

13. Lin Tang,* Zhen Yang, Xueping Chang,* Jingchao Jiao, Xiantao Ma, Weihao Rao, Qiuju Zhou, Lingyun Zheng, K2S2O8-Mediated Selective Trifluoromethylacylation and Trifluoromethylarylation of Alkenes under Transition Metal-Free Conditions:Synthetic Scope and Mechanistic Studies, Org. Lett. 2018, 20, 6520.

14. Lin Tang,* Zhen Yang, Tian Sun, Di Zhang, Xiantao Ma,* Weihao Rao, Yuqiang Zhou, Unexpected Decarboxylation-Triggered o-Hydroxyl-Controlled Redox Condensation of Phenylglycines with 2-Nitrophenols in Aqueous Media, Adv. Synth. Catal. 2018, 360, 3055.

15. Lin Tang,* Zhen Yang, Xueping Chang, Guodong Zou, Yuqiang Zhou, Weihao Rao,* Xiantao Ma, Geng Zhao, Water-controlled nitro-oximation of alkenes under catalyst-free conditions, Tetrahedron Lett. 2018, 59, 4272.

16. Lin Tang,* Lixian Wen, Tian Sun, Di Zhang, Zhen Yang, Chengtao Feng, and Zhiyong Wang*, Solvent-Controlled Copper-Catalyzed Radical Decarboxylative Coupling for Alkenyl C(sp2)-P Bond Formation, Asian J. Org. Chem. 2017, 6, 1683.

17. Lin Tang*, Yu Yang, Lixian Wen, Xingkun Yang, and Zhiyong Wang*, Catalyst-free radical fluorination of sulfonyl hydrazides in water, Green Chem. 2016, 18, 1224.

18. Lin Tang,* Xianghua Zhao, Guodong Zou, Yuqiang Zhou, and Xingkun Yang, Heterogeneous Gold-Catalyzed Cascade Hydrogen-Transfer Strategy for Selective Synthesis of Quinazolinones in Water, Asian J. Org. Chem. 2016, 5, 335.

19. Lin Tang,* Pengfei Wang, Yang Fan, Xingkun Yang, Changfeng Wan,* and Zhenggen Zha, Heterogeneous Palladium-Catalyzed Hydrogen-Transfer Cyclization of Nitroacetophenones with Benzyl Amines: Access to C-N Bonds, ChemCatChem 2016, 8, 3565.

20. Lin Tang, Yu Yang, Lixian Wen, Sheng Zhang, Zhenggen Zha, and Zhiyong Wang*, Supported gold-catalyzed and ammonia-promoted selective synthesis of quinazolines in aqueous media, Org. Chem. Front. 2015, 2, 114.

21. Lin Tang, Xuefeng Guo, Yu Yang, Zhenggen Zha, and Zhiyong Wang*, Gold nanoparticles supported on titanium dioxide: an efficient catalyst for highly selective synthesis of benzoxazoles and benzimidazoles, Chem. Commun. 2014, 50, 6145.

22. Lin Tang, Xuefeng Guo, Yunfeng Li, Shuai Zhang, Zhenggen Zha, and Zhiyong Wang*, Pt, Pd and Au nanoparticles supported on a DNA-MMT hybrid: efficient catalysts for highly selective oxidation of primary alcohols to aldehydes, acids and esters, Chem. Commun. 2013, 49, 5213.

23. Lin Tang, Huayin Sun, Yunfeng Li, Zhenggen Zha, and Zhiyong Wang*, Highly active and selective synthesis of imines from alcohols and amines or nitroarenes catalyzed by Pd/DNA in water with dehydrogenation, Green Chem. 2012, 14, 3423.

24. Lixian Wen, Lin Tang(共同第一作者), Yu Yang, Zhenggen Zha, and Zhiyong Wang,* Ligand-free Pd-catalyzed domino synthesis of carbazoles via dehydrogenative aromatization/C(sp2)–C(sp2) coupling sequence, Org. Lett. 2016, 18, 1278.

25. Xuefeng Guo, Lin Tang(共同第一作者), Yu Yang, Zhenggen Zha, and Zhiyong Wang*, An efficient synthesis of amides from alcohols and azides catalyzed by a bifunctional catalyst Au/DNA under mild conditions, Green Chem. 2014, 16, 2443.